REP(-) plus CH3O(-) TS     46 REP(-) plus CH3O(-) TS

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    #  Species Formula
    36 1b Nitrous oxide and acetylene TSC2H2N2O
    37 1a Nitrous oxide and ethylene TSC2H4N2O
    38 H plus HF - HF plus H TSH2F
    39 H plus FCH3 - HF plus CH3 TSCH4F
    40 F-CH3-OH (-) TSCH4OF
    41 HOCH3F TS 2CH4OF
    42 OH(-) plus CH3F - HOCH3 plus F(-) TSCH4OF
    43 HF2 TSHF2
    44 FCH3F TS 1CH3F2
    45 EP(-) plus CH3O(-) TSC3H7O5P
    46 REP(-) plus CH3O(-) TS C5H9O6P
    47 HClH TSH2Cl
    48 CH3 plus FCl - CH3F plus Cl TSCH3FCl
    49 F - CH3 - Cl(-) TS, forward reactionCH3FCl
    50 FCH3Cl TS 1CH3FCl
    51 Cl-CH3-Cl (-) TSCH3Cl2
     1 H plus C2H4 - CH3CH2 TSC2H5
     2 CH3 plus C2H4 - CH3CH2CH2 TSC3H7
     3 hc1 - Ring-opening cyclobutene TSC4H6
     4 hc5 - Cyclobutadiene TSC5H6
     5 hc4 - Pentadiene TSC5H8


ΔHf: 82.0 kcal/mol,     REF: Lopez, X., Dejaegere, A., Leclerc, F., York, D. M., Karplus, M., "Nucleophilic Attack on Phosphate Diesters: A Density Functional Study of In-Line Reactivity in Dianionic, Monoanionic, and Neutral Systems" J. Phys. Chem. B, 2006, 110, 11
  
 CHARGE=-2
      REP(-) plus CH3O(-) TS
      h=81.97+"REP (2',3'-cyclic ribose ethylene phosphate anion)"+"CH3O(-)" hr=LDLY2006
  C     0.00000000  0    0.0000000  0    0.0000000  0     0     0     0
  C     1.57020000  1    0.0000000  0    0.0000000  0     1     0     0
  O     1.38002100  1  108.8380170  1    0.0000000  0     1     2     0
  O     1.42875400  1  108.3499280  1   -0.1478760  1     2     1     3
  P     1.65197800  1  115.6660250  1    0.2563770  1     4     2     1
  O     1.49609200  1  114.2917920  1  103.9725230  1     5     4     2
  O     1.49349800  1  115.2870070  1  150.2080590  1     5     4     6
  H     1.10661100  1  113.4514510  1 -120.3917180  1     1     2     3
  C     1.55551500  1  103.7794320  1 -120.9599860  1     1     2     8
  C     1.54002700  1  104.4080970  1 -118.2985720  1     2     1     4
  H     1.10129900  1  113.7588470  1 -122.5905990  1     2     1    10
  H     1.10116100  1  111.1921260  1 -101.9511720  1     9     1     2
  H     1.09240900  1  113.9760600  1 -126.2634470  1     9     1    12
  H     1.10345500  1  111.6406760  1  101.7112220  1    10     2     1
  H     1.09402200  1  114.1679180  1  126.5454420  1    10     2    14
  O     1.42628100  1  107.6465640  1 -115.6552720  1     9     1    13
  O     2.09183200  1  159.3982320  1 -175.8539940  1     4     2     5
  C     1.35395700  1  101.8418790  1  -61.3939360  1    17     4     2
  H     1.11060600  1  109.1633690  1  164.0032950  1    18    17     4
  H     1.10263200  1  112.8108360  1  119.1670030  1    18    17    19
  H     1.10594500  1  111.8846940  1  122.0268720  1    18    17    20